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Fluorescence spectrum of the benzene radical cation in solid argon

โœ Scribed by J.Houston Miller; Lester Andrews


Publisher
Elsevier Science
Year
1980
Tongue
English
Weight
433 KB
Volume
72
Category
Article
ISSN
0009-2614

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โœฆ Synopsis


Argon/benzene samples were condensed at I Z K with contmuous argon resonance radlatlon Laser excitation af 421 nm produced a weak emlsslon with structure at 19770, 19140 and 18290 cm-l, assrgned to the 'A,,-2E,gemlssron of CBHz Obser\atron of 630 and 1480 cm-' mtervals for the vibrations ~, a (e,,) andv,~ (e,,). respectively. supports this assignment


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By means of the reaction of atomic H or D (produced either in a microwave discharge or on a W filament) with cithcr NO2 or 0, or atomic 0, we have prepared and trapped OH and OD radicals In sohd Ar at 12 K. characterized by their infrared absorption lines at 354820 and 26 I610 m-'. resuectivelv. The