๐”– Bobbio Scriptorium
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Infrared spectra recording, high pressure sample holder


Publisher
Elsevier Science
Year
1991
Tongue
English
Weight
94 KB
Volume
47
Category
Article
ISSN
1386-1425

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Far-infrared spectra of solid CH4 under
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Far-infrared spectra of solid CH4 have been recorded at 4.2 K under pressure, P = 0.4 kbar (phase Ii) and P = 4.5 kbar (phase III). In phase IL two bands have been observed at 53 and 76 cm-', while in phase IIi three bands have been seen at 65,70 and 94 cm-'\_ Lattice dynamical calcr?htions for the

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## Laser-excited Raman spectra have been obtained of samples while subjected to very high pressure (up to twenty kilobars). Cpposed diamond anvil pressure cells and commercial Raman spectrometers are used for these experiments. Such Raman data provide a very sensitive probe for determining the ef