The far-infrared of DCI, HCl and HF in liquid SF, (T= 273 K) are studied by applying a previously reported non-Markovian line-by-line spectral theory in which memory and mixing effects arc explicitly considered. We analyze the importance of both effects in terms of the rotational constant of the dia
Infrared spectra HCl and DCl in SF6 matrices
β Scribed by R. Ranganath; T.E. Whyte Jr.; T. Theophanides; G.C. Turrell
- Book ID
- 113371568
- Publisher
- Elsevier Science
- Year
- 1967
- Tongue
- English
- Weight
- 179 KB
- Volume
- 23
- Category
- Article
- ISSN
- 1386-1425
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π SIMILAR VOLUMES
The far infrared spectrum of dilute solutions of HCl and DC1 dissolved in liquid SF6 at OΒ°C is observed in the frequency region 30 cm-1 to 230 cm-l. A broad absorption band is obtained for DC1 which is in excellent agreement with the band envelope defined by the relative integrated intensity of each
The spectra of HCl and DC1 molecules trapped in 3 nitrogen matrix were studied in the 100~250cm-L spectral region. Two absorptions were observed for each species: at 154 and 207cm-L for EfCL and at 132 and 162cm-1 for DCI. These &sorption showed monomeric behaviour. They are 'assigned to librationtr
The fundamental infrared spectra (2700-3100 cm-') of dilure solutions of HCI in liquid SF, at temperatures between 2 18 and 316 K have been calculated by applying a spectral theory based on the decomposition of the rotational motion of the diatomic molecule into two limiting cases: quasi-free rotati