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Pure rotational spectrum of HCl and DCl in liquid SF6

✍ Scribed by George Birnbaum; W. Ho

Publisher
Elsevier Science
Year
1970
Tongue
English
Weight
311 KB
Volume
5
Category
Article
ISSN
0009-2614

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✦ Synopsis

The far infrared spectrum of dilute solutions of HCl and DC1 dissolved in liquid SF6 at OΒ°C is observed in the frequency region 30 cm-1 to 230 cm-l. A broad absorption band is obtained for DC1 which is in excellent agreement with the band envelope defined by the relative integrated intensity of each of the pure rotational transitions in the gas phase. The HCl spectrum. however. shows clearly resolved lines superimposed on a broad absorption ba;.d. These lines are readily identifiable with the pure rotational lines in

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