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Memory and nonadditivity effects on the far-infrared spectra of DCl, HCl and HF in liquid SF6

✍ Scribed by A. Medina; J.M.M. Roco; S. Velasco; A. Calvo Hernández


Publisher
Elsevier Science
Year
1993
Tongue
English
Weight
557 KB
Volume
202
Category
Article
ISSN
0009-2614

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✦ Synopsis


The far-infrared of DCI, HCl and HF in liquid SF, (T= 273 K) are studied by applying a previously reported non-Markovian line-by-line spectral theory in which memory and mixing effects arc explicitly considered. We analyze the importance of both effects in terms of the rotational constant of the diatomic molecule. Moreover, the influence of mixing effects on the observed resolved rotational structure is discussed.


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