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Infrared laser induced chemistry: Reactions of difluoromethane

โœ Scribed by S.T. Lin; A.M. Ronn

Publisher
Elsevier Science
Year
1977
Tongue
English
Weight
425 KB
Volume
49
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

Reactions of CH2F2 excited in its C-F stretching mode by a TEA CO 2 laser have been investigated. Chemical reactions of the excited species in the neat show evidence of the difluorocarbene radical involvement. Reactions with molecular chlorine display at least two distinct mechanisms at different pressure regimes. Comparisons are made with other uninlolecular dissociations and bimolecular reactions induced by multiphoton absorptions from similar laser sources.

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