Rates of V-T transfer for vibrationally excited ozone (Oi) in the (loo), ( 010) and ( 001) levels have been measured using a laser enhanced chemiluminescent method for the deactivating gases He, Ar, Hz, N2,02, H20, CO2, SO2, CH4, and SF6. The method takes advantage of an enhanced reaction rate betwe
โฆ LIBER โฆ
J4 Infrared laser enhanced reactions: chemistry of vibrationally excited no with O3
โ Scribed by John C. Stephenson; Samuel M. Freund
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 80 KB
- Volume
- 18
- Category
- Article
- ISSN
- 0030-4018
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The rate constants for the reactions SiH,+02, SiH,+NO, and StH,+NO+N, have been measured over the pressure range I-10 Torr at 300 K, by monitoring a SiHl absorption line at 7 19.93 I cm ' using time-resolved diode laser spectroscopy. SiH3 radicals were prepared by pulsed CO2 laser photolysis of CClz