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Infrared evidence of a β-hairpin peptide structure in solution

✍ Scribed by JoséLuis R. Arrondo; Francisco J. Blanco; Luis Serrano; Félix M. Goñi

Book ID
115932224
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
338 KB
Volume
384
Category
Article
ISSN
0014-5793

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Synthesis and conformational studies of two short peptides containing pyrrole amino acids (1, Paa), Boc-Paa-Paa-D-Pro-Gly-Xaa-Paa-Paa-OMe (2: Xaa=Ala; 3: Xaa=Val), were carried out in which it was established that replacement of Ala in 2 with a Val residue helps peptide 3 to adopt a well-defined b-h