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Infrared-Emission Studies of Electronic-to-Vibrational Energy Transfer IV: Hg* + HF

โœ Scribed by Heydtmann, H. ;Polanyi, J. C. ;Taguchi, R. T.

Book ID
115321819
Publisher
The Optical Society
Year
1971
Tongue
English
Weight
676 KB
Volume
10
Category
Article
ISSN
1559-128X

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๐Ÿ“œ SIMILAR VOLUMES

Electronic-to-vibrational energy transfe
Electronic-to-vibrational energy transfer in a collision of CO with Hg(3PO)
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The cncrgy -rransfcr process, H&P,) f CO(O) -Hg('S~)+CO(v),hnsbccn nudisd by tie mexurcmen~oCthcLR flubrescerlce of CO. urine modulafed H&resonant radiation to excite Hg atoms. The cross section for each final vibrationallevelof v = 2 to 9 is 0.045, 0.091, 0.15, 0.17, 0.15, 0.065, 0.013, and 0.006 A

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Collisional transfer of electronic energy from spin-orbit excited chlorine atoms, Cl\* [ ~P'(~P,,~) ] (E=882 cm-'), to vibrational energy in SOz has been observed by time-resolved infrared fluorescence from the fundamental SOI stretching levels. The rate constant ( k la) for Cl\* quenching by SO2 at

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Quenching of electronic eaciration by collisional transfer into vibration is quantirativrly truared. assuming sudden release of the escitation near the classical turning point. For the H, o\*-sensitized ZR fluorescence of CO, the calculated vibrational distribution reproduces the experimental result