Dynamical theory of vibrational state population distribution in electronic-to-vibrational energy transfer. Application to Hg*-sensitized IR fluorescence of diatomics

✍ Scribed by R.D. Levine; R.B. Bernstein

• Publisher: Elsevier Science
• Year: 1972
• Tongue: English
• Weight: 539 KB
• Volume: 15
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(72)87001-5

✦ Synopsis

Quenching of electronic eaciration by collisional transfer into vibration is quantirativrly truared. assuming sudden release of the escitation near the classical turning point. For the H, o*-sensitized ZR fluorescence of CO, the calculated vibrational distribution reproduces the experimental results of Polanyi et al.