Time-resolved infrared fluorescence observations of the Bf (4 'P,,,) spin-orbit excited state and the SO2 symmetric (v,) and antisymmetric (vl) stretching modes have been obtained following 532 nm laser photolysis of Br2/S02 and IBr/S02 mixtures. The total Bf quenching rate coefkient by SO\* was det
โฆ LIBER โฆ
Infrared fluorescence study of electronic-to-vibrational energy transfer in the Br(2P12)-NO system
โ Scribed by Michael R. Hawks; Ray O. Johnson; Glen P. Perram
- Book ID
- 107942959
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 436 KB
- Volume
- 195
- Category
- Article
- ISSN
- 0301-0104
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Collisional transfer of electronic energy from spin-orbit excited chlorine atoms, Cl\* [ ~P'(~P,,~) ] (E=882 cm-'), to vibrational energy in SOz has been observed by time-resolved infrared fluorescence from the fundamental SOI stretching levels. The rate constant ( k la) for Cl\* quenching by SO2 at
Numerical Methods in Gas Dynamics. Edite