11i Chcrnisf~~. L'ln%ws& of Colorado\_ Boulder. Colorado SO309. USA \'ihr;ltional ctl~mi1unlinesccnc-c is dercctcd from the reaction N\*("P) i-Oz(S"Q in a flowing -after~lo\v. The atomtrnnsfcr product. NO+(X ' 1.+. u). displays a bimodal vibrationaldistribution spanning the nnge v = l-14. Excited N(
Infrared Chemiluminescence from the Gaseous Reaction Atomic H. Plus NO; HNO in Emission
โ Scribed by Cashion, J. K.; Polanyi, J. C.
- Book ID
- 120277251
- Publisher
- American Institute of Physics
- Year
- 1959
- Tongue
- English
- Weight
- 479 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-9606
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๐ SIMILAR VOLUMES
The same chemiluminescent spectrum of HNO was obtained in both the reaction systems of 0(3P) + CaHe + NO + 02 (\* A,)/02 and H + NO + 02( 'Ag)/Oa. The reaction mechanism for producing the excited HNO is proposed to be -HNO('A') + 02 ( 'Ag) + HNO(3A", + 0s (3X,) , HNOc3A") + 02 ('A,) --t HNO('A") +
Arrested rekxation infrared chemiluminescence studies of the H + Cl,, SCl2, !5&12, SCQ and SO&l2 reactions have been made. ihe mean fraction of vibrational fi a~ational) enem released to HCl is 0.40(0.10); 0.40(0.13); 0.38(?0.02); 0.33(?0.02) and 036 (20.02) for the series. Only the H + SC12 reactio