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Infrared and raman spectra of magnus' green salt, [Pt(NH3)4] [PtCl4], and its deuterate

โœ Scribed by J.R. Hall; D.A. Hirons

Publisher
Elsevier Science
Year
1979
Tongue
English
Weight
193 KB
Volume
34
Category
Article
ISSN
0020-1693

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โœฆ Synopsis

Infrared and Raman Spectra of Magnus' Green Salt, [Pt(NH&] [PtCl,] , and Its Deuterate

sample was lowered from ambient to liquid nitrogen temperature. Initially the band was assigned [2] to the Aa,, translational lattice mode involving the chain of Pt atoms in the columnar array of cations and anions . The frequency of 200 cm-' was considered too high for this mode and it was reassigned to NH3 torsional motion [l] .

Confirmation of this assignment has been achieved by recording the far infrared spectrum of the deuterated salt. The Raman spectrum of the deuterate has also been obtained.

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