Infrared absorption spectra of SiH2Cl2, SiDHCl2 and SiD2Cl2
β Scribed by Daniel H. Christensen; Ole F. Nielsen
- Publisher
- Elsevier Science
- Year
- 1968
- Tongue
- English
- Weight
- 547 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0022-2852
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The \(b\)-type rotational spectrum of \({ }^{28} \mathrm{SiH}_{2}{ }^{35} \mathrm{Cl}_{2}\) has been remeasured in the frequency region 10.3-15.7 GHz \((J=1-10)\) using a microwave Fourier transform (MWFT) cavity spectrometer. The MWFT technique has permitted resolution of the complex hyperfine patt
Laser-excited fluorescence detection of HSiCl was used to measure the room-temperature kinetics of the reactions of HSiCl with SiH, and Sic&HZ. An upper bound was also obtained for the HSiCl+Hz rate coefficient. Rate coefftcients for insertion of HSiCl into SiH., and SiC12H2 are 3-4 orders of magnit