Infrared and Raman spectra of fluorinated ethanes: Part XVII. CF2ClCH2Cl and CF2BrCH2Br
✍ Scribed by H.P. Bucker; J.Rud Nielsen
- Publisher
- Elsevier Science
- Year
- 1963
- Tongue
- English
- Weight
- 887 KB
- Volume
- 11
- Category
- Article
- ISSN
- 0022-2852
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A variety of relative and absolute techniques have been used to measure the reactivity of fluorine atoms with a series of halogenated organic compounds and CO. The following rate constants were derived, in units of cm3 molecule-' s-l: CH3F, (3.7 2 0.8) X CH3C1, (3.3 2 0.71 X 10 -'I; CH3Br, (3.0 2 0.
An analysis of thermochemical and kinetic data on the bromination of the halomethanes CH, ,X,, (X = F, C1, Br; n = 1-31, the two chlorofluoromethanes, CH,FCI and CHFCl,, and CH,, shaws that the recently reported heats of formation of the radicals CH2C1, CHClz, CHBr2, and CFC12, and the C-H bond diss