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Influence of polarity of the medium on the catalysis of formation and stability of the Schiff base from pyridoxal 5'-phosphate and n-hexylamine

✍ Scribed by M.Angeles Garcísa Del Vado; Gerado R. Echevarria; Alfredo García-Espantaleon; Josefa Donoso; Francisco Muñoz; Francisco García Blanco

Publisher
Elsevier Science
Year
1988
Weight
677 KB
Volume
44
Category
Article
ISSN
0304-5102

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Influence of the side chain on the stabi
Influence of the side chain on the stability of Schiff-bases formed between pyridoxal 5′-phosphate and amino acids
✍ M. A. Vazquez; F. Muñoz; J. Donoso; F. García Blanco 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 527 KB

## Abstract The stability of some Schiff‐bases formed between PLP and different amino acids has been investigated in a wide range of pH. The kinetic constants of formation of these compounds and their hydrolysis rate constants have been determined. Results show that the α‐position of the carboxyl g

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On the Stability of the Schiff Bases of Pyridoxal 5′-Phosphate with Polypeptides Containing L-Lysine
✍ M. Angeles García del Vado; Gerardo R. Echevarria; Francisco García Blanco; José 📂 Article 📅 1991 🏛 John Wiley and Sons 🌐 German ⚖ 506 KB

We determined the apparent equilibrium constant of formation, KpH, of the Schijf bases of pyridoxal 5'-phosphate (PLP) and poly-and copolymers containing L-lysine, as a function of pH at 25" and a constant ionic strength of 0 . 1 ~. The KPH values obtained at acidic and neutral pH were larger that t