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Electrochemical behaviour of the Schiff base from pyridoxal-5'-phosphate and L-alanine

✍ Scribed by T. Pineda; M. Blázquez; M. Dominguez; F. Garcia-Blanco

Publisher
Elsevier Science
Year
1990
Weight
771 KB
Volume
294
Category
Article
ISSN
0022-0728

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We determined the apparent equilibrium constant of formation, KpH, of the Schijf bases of pyridoxal 5'-phosphate (PLP) and poly-and copolymers containing L-lysine, as a function of pH at 25" and a constant ionic strength of 0 . 1 ~. The KPH values obtained at acidic and neutral pH were larger that t

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The formation constants of the Schiff bases of pyridoxal %-phosphate with polyallylamine were determined over the pH range of the acetic-acetate buffer (3.9-5.5) a t an ionic strength of 0.1 M and a temperature of 25°C. The results were consistent with the rapid formation of an ionized carbinolamine