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Influence of Charge Transfer Interactions on the Sensitization of Singlet Oxygen: Formation of O 2 ( 1 Σ g+ ), O 2 ( 1 Δ g ), and O 2 ( 3 Σ g- ) during Oxygen Quenching of Triplet Excited Biphenyl Derivatives

✍ Scribed by Schmidt, Reinhard; Shafii, Farokh


Book ID
126094156
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
101 KB
Volume
105
Category
Article
ISSN
1089-5639

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Time-resolved emission spectroscopy of 0s ( 'Z: ) and 0s ( 'As) in CCL was used to determine the rate constants kl, , b, and k+ of the triplet state (T,) sensitized formation of the 'Z:, 'As and 'Z; states of 0s. 13 sensitizers of triplet energies 140 GE,< 309 kJ mol-' were investigated. The data ar