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Formation of O 2 ( 1 Σ g+ ), O 2 ( 1 Δ g ), and O 2 ( 3 Σ g- ) during Oxygen Quenching of nπ* Triplet Phenyl Ketones: The Role of Charge Transfer and Sensitizer-Oxygen Complex Structure

✍ Scribed by Mehrdad, Zahra; Schweitzer, Claude; Schmidt, Reinhard


Book ID
125950895
Publisher
American Chemical Society
Year
2002
Tongue
English
Weight
111 KB
Volume
106
Category
Article
ISSN
1089-5639

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Time-resolved emission spectroscopy of 0s ( 'Z: ) and 0s ( 'As) in CCL was used to determine the rate constants kl, , b, and k+ of the triplet state (T,) sensitized formation of the 'Z:, 'As and 'Z; states of 0s. 13 sensitizers of triplet energies 140 GE,< 309 kJ mol-' were investigated. The data ar