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Influence of “bath” modes on the non-Condon effect

✍ Scribed by H. Hornburger

Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
365 KB
Volume
143
Category
Article
ISSN
0009-2614

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✦ Synopsis

S, *So internal conversion transitions are calculated as a function of the energy gap. With data for benzene and deuterobenzene, it is shown that rates obtained in the nonCondon case with a complete basis set lead to a relative rate increase about two orders of magnitude smaller than earlier results. A factor of only 2-3 for the S, *So transition seems to be operative when the non-Condon formalism is introduced.

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