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Inexpensive, One-Pot Synthesis of Unsymmetrical Disulfides Using 1-Chlorobenzotriazole

โœ Scribed by Hunter, Roger; Caira, Mino; Stellenboom, Nashia


Book ID
119993844
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
94 KB
Volume
71
Category
Article
ISSN
0022-3263

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โœ Barahman Movassagh; Mozhgan Navidi ๐Ÿ“‚ Article ๐Ÿ“… 2008 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 161 KB

A simple, general, and highly regioselective procedure has been developed for the one-pot synthesis of b-hydroxysulfides in good yields from various styrenes and disulfides by cleavage of the S-S bond with a Zn/AlCl 3 system in aqueous acetonitrile at 80 ยฐC and in the presence of oxygen.