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Indium Metal as a Reducing Agent. Selective Reduction of the Carbon−Carbon Double Bond in Highly Activated Conjugated Alkenes

✍ Scribed by Ranu, Brindaban C.; Dutta, Jyotirmoy; Guchhait, Sankar K.


Book ID
111931577
Publisher
American Chemical Society
Year
2001
Tongue
English
Weight
46 KB
Volume
3
Category
Article
ISSN
1523-7060

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Use of indium hydride (Cl2InH) for chemo
✍ Brindaban C. Ranu; Sampak Samanta 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 81 KB

Indium hydride (Cl 2 InH) generated in situ from a combination of a catalytic amount of indium(III) chloride and sodium borohydride selectively reduces the carbon carbon double bond in conjugated alkenes such as a,a-dicyano olefins, a,b-unsaturated nitriles, cyano esters, cyanophosphonate, diesters