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Use of Indium Hydride (Cl2InH) for Chemoselective Reduction of the Carbon—Carbon Double Bond in Conjugated Alkenes.

✍ Scribed by Brindaban C. Ranu; Sampak Samanta

Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
33
Category
Article
ISSN
0931-7597

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📜 SIMILAR VOLUMES

Use of indium hydride (Cl2InH) for chemo
Use of indium hydride (Cl2InH) for chemoselective reduction of the carboncarbon double bond in conjugated alkenes
✍ Brindaban C. Ranu; Sampak Samanta 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 81 KB

Indium hydride (Cl 2 InH) generated in situ from a combination of a catalytic amount of indium(III) chloride and sodium borohydride selectively reduces the carbon carbon double bond in conjugated alkenes such as a,a-dicyano olefins, a,b-unsaturated nitriles, cyano esters, cyanophosphonate, diesters

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## Abstract A novel efficient and eco‐friendly nanocrystalline ZnO catalyst was used for the __Knoevenagel__ condensation and for the reduction of CC double bonds at room temperature in the absence of solvents.