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Use of indium hydride (Cl2InH) for chemoselective reduction of the carboncarbon double bond in conjugated alkenes

✍ Scribed by Brindaban C. Ranu; Sampak Samanta

Publisher: Elsevier Science
Year: 2002
Tongue: French
Weight: 81 KB
Volume: 43
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(02)01668-4

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✦ Synopsis

Indium hydride (Cl 2 InH) generated in situ from a combination of a catalytic amount of indium(III) chloride and sodium borohydride selectively reduces the carbon carbon double bond in conjugated alkenes such as a,a-dicyano olefins, a,b-unsaturated nitriles, cyano esters, cyanophosphonate, diesters and ketones.

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