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Indium in organic synthesis: indium-mediated allylation of carbonyl compounds

✍ Scribed by Araki, Shuki; Ito, Hirokazu; Butsugan, Yasuo


Book ID
111877474
Publisher
American Chemical Society
Year
1988
Tongue
English
Weight
324 KB
Volume
53
Category
Article
ISSN
0022-3263

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πŸ“œ SIMILAR VOLUMES


Indium mediated allylation of Cξ˜…N compou
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Allylindium adds to a variety of tosyl and aryl hydrazones derived from aromatic aldehydes and ketones at ambient temperature in a DMF-H 2 O solvent system to afford homoallylic tosyl hydrazides and homoallylic hydrazines, respectively. Homoallylic hydroxylamines were isolated via addition of allyli

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Bromocyanomethylation of a variety of carbonyl compounds to produce the corresponding 2-bromo-3hydroxynitriles has been achieved in moderate to good yields by the action of dibromoacetonitrile and indium(I) bromide. Moderate diastereoselectivity was observed. Exclusive mono-coupling at the carbonyl

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