Indium mediated allylation of CN compounds in aqueous media

✍ Scribed by H.M Sampath Kumar; S Anjaneyulu; E Jagan Reddy; J.S Yadav

• Publisher: Elsevier Science
• Year: 2000
• Tongue: French
• Weight: 55 KB
• Volume: 41
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(00)01676-2

✦ Synopsis

Allylindium adds to a variety of tosyl and aryl hydrazones derived from aromatic aldehydes and ketones at ambient temperature in a DMF-H 2 O solvent system to afford homoallylic tosyl hydrazides and homoallylic hydrazines, respectively. Homoallylic hydroxylamines were isolated via addition of allylindium to aldonitrones.