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Indium(I) bromide-mediated bromocyanomethylation of carbonyl compounds

✍ Scribed by J.A. Nóbrega; Simone M.C. Gonçalves; C. Peppe

Book ID: 104210601
Publisher: Elsevier Science
Year: 2000
Tongue: French
Weight: 149 KB
Volume: 41
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)00960-6

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✦ Synopsis

Bromocyanomethylation of a variety of carbonyl compounds to produce the corresponding 2-bromo-3hydroxynitriles has been achieved in moderate to good yields by the action of dibromoacetonitrile and indium(I) bromide. Moderate diastereoselectivity was observed. Exclusive mono-coupling at the carbonyl group was found with 1,2-diketones and a-haloketones.

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## Abstract For Abstract see ChemInform Abstract in Full Text.