Including methyl rotation in simulations of spin-lattice relaxation experiments
β Scribed by E.T Olejniczak
- Publisher
- Elsevier Science
- Year
- 1989
- Weight
- 180 KB
- Volume
- 81
- Category
- Article
- ISSN
- 0022-2364
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SelectIre NhlR TI mrasurements on dcutermm m pouders rotatrng at high speed at the magtc angle mdtcate that dlpolat spm dlffusmn ~~hich can bc quenched by the ortentattonal dependence of the quadrupole spbttmg, IS partially restored by the simple rotatton
The present paper reports the achievement of the rotating-frame analog of spin-locking and its application to the precise measurements of the spin-lattice relaxation time T(1DR) in the doubly rotating frame. After the magnetization is aligned along the resonant RF field H(1), a pulse sequence of a l
## Abstract The application of rotating frame spinβlattice relaxtion to the determination of the intramolecular motions in peptides is discussed, and results are presented on the application of ^13^C __T__~1__p__~ to peptide microdynamics in solution. The effective molecular rotational reorientatio