Rotating Frame Analog of Spin-Locking and Spin–Lattice Relaxation in the Doubly Rotating Frame

✍ Scribed by Noriyuki Tabuchi; Hiroshi Hatanaka

• Publisher: Elsevier Science
• Year: 2001
• Tongue: English
• Weight: 79 KB
• Volume: 148
• Category: Article
• ISSN: 1090-7807
• DOI: 10.1006/jmre.2000.2217

✦ Synopsis

The present paper reports the achievement of the rotating-frame analog of spin-locking and its application to the precise measurements of the spin-lattice relaxation time T(1DR) in the doubly rotating frame. After the magnetization is aligned along the resonant RF field H(1), a pulse sequence of a low-frequency oscillating magnetic field at exact resonance is applied perpendicular to H(1). We have overcome several technical difficulties arising from the fact that the rotating-wave approximation is not valid for the low-frequency field. We have theoretically derived an expression of T(-1)(1DR) due to fluctuating magnetic dipole interactions in the weak collision case and found an important relation among the spin-lattice relaxation rates T(-1)(1), T(-1)(1rho), and T(-1)(1DR). This relation can be used to ascertain whether the relaxation is only due to the fluctuating magnetic dipole interactions between like spins. The experiment was carried out on (1)H nuclei in tetramethylammonium iodide (CH(3))(4)NI and the temperature dependence of T(-1)(1DR) was measured together with that of T(-1)(1) and T(-1)(1rho). The activation energies and the preexponential factors of Arrhenius expressions of the correlation times are newly determined.