In- or In(I)-Employed Tailoring of the Stereogenic Centers in the Reformatsky-Type Reactions of Simple Ketones, α-Alkoxy Ketones, and β-Keto Esters
✍ Scribed by Babu, Srinivasarao Arulananda; Yasuda, Makoto; Shibata, Ikuya; Baba, Akio
- Book ID
- 121499370
- Publisher
- American Chemical Society
- Year
- 2005
- Tongue
- English
- Weight
- 472 KB
- Volume
- 70
- Category
- Article
- ISSN
- 0022-3263
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Reformatsky-Type Addition of Esters of α-Halogeno Carboxylic Acids to Aldehydes and Ketones in the Presence of Fe(CO) 5 . -Fe(CO) 5 -promoted Reformatsky-type addition of α-halogenocarboxylates to carbonyl compounds affords the corresponding β-hydroxycarboxylates (III) (12 examples) in moderate to