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ChemInform Abstract: Reformatsky-Type Addition of Esters of α-Halogeno Carboxylic Acids to Aldehydes and Ketones in the Presence of Fe(CO)5.

✍ Scribed by A. B. Terent'ev; T. T. Vasil'eva; N. A. Kuz'mina; E. I. Mysov; N. S. Ikonnikov; N. Yu. Kuznetsov; Yu. N. Belokon

Publisher
John Wiley and Sons
Year
2010
Weight
37 KB
Volume
30
Category
Article
ISSN
0931-7597

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✦ Synopsis

Reformatsky-Type Addition of Esters of α-Halogeno Carboxylic Acids to Aldehydes and Ketones in the Presence of Fe(CO) 5 .

-Fe(CO) 5 -promoted Reformatsky-type addition of α-halogenocarboxylates to carbonyl compounds affords the corresponding β-hydroxycarboxylates (III) (12 examples) in moderate to good yields. α-Polyhalogenated carboxylates (IV) react substantially different under similar conditions and provide esters of substituted acrylic acids (VI)/(VII). -(TERENT'EV, A.

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