Improved stereochemical control and mechanistic aspects of the alkylation of enolates derived from [(η5-C5H5)Fe(CO)(PPh3)COCH2R]
✍ Scribed by Stephen L. Brown; Stephen G. Davies; Douglas F. Foster; Jeffrey I. Seeman; Peter Warner
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 229 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
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📜 SIMILAR VOLUMES
The lithium enolate derived from the homochiral iron acetyl complex S-[(q5-C5H5)-Fe(CO)(PPh3)COCH3] reacts preferentially (40: 1) with the R-enantiomer of racemic t-butyl 2bromopropionate.
## Surnmnry: The enantiomerically pure iron acyl complex R-(-)-[($-CSH5)Fe(CO)(PPh3)-CUCH20({lR,2S,5R]menthyl))] tepresents a source of homochiral formyl anion equivalent applicable to the synthesis of enantiomerkally pare a-hydroxy acetals from aldehydes. The formyl anion or a synthetic equivale
## Application of the Iron Acyl Complex (S)-(+)-[(115-CsHs)Fe(CO)(PPh3)COCHzPh] as a Homochiral Phenylacetate Enolate Equivalent,