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Asymmetric synthesis of (S)-(−)-methyl tropinate: application of the iron acyl complex (S)-(+)-[(η5-C5H5)Fe(CO)(PPh3)COCH2Ph] as a homochiral phenylacetate enolate equivalent.

✍ Scribed by Teresa M Baker; Graham J Bodwell; Stephen G Davies; Alison J Edwards; Michael R Metzler

Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 892 KB
Volume: 49
Category: Article
ISSN: 0040-4020
DOI: 10.1016/s0040-4020(01)87273-2

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✦ Synopsis

Application of the Iron Acyl Complex (S)-(+)-[(115-CsHs)Fe(CO)(PPh3)COCHzPh] as a Homochiral Phenylacetate

Enolate Equivalent,

📜 SIMILAR VOLUMES

Application of the iron acyl complex R-(

Application of the iron acyl complex R-(-)-[(η5-C5H5)Fe(CO)(PPh3)- COCH2O({{1R,2S}},5Rmenthyl)] as a homochiral formyl anion equivalent

✍ Stephen G. Davies; David Middlemiss; Alan Naylor; Martin Wills 📂 Article 📅 1989 🏛 Elsevier Science 🌐 French ⚖ 307 KB

## Surnmnry: The enantiomerically pure iron acyl complex R-(-)-[($-CSH5)Fe(CO)(PPh3)-CUCH20({lR,2S,5R]menthyl))] tepresents a source of homochiral formyl anion equivalent applicable to the synthesis of enantiomerkally pare a-hydroxy acetals from aldehydes. The formyl anion or a synthetic equivale