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Chiral recognition in the SN2 reaction of t-butyl 2-bromopropionate with the enolate derived from [(γ5−C5H5)Fe(CO)(PPh3)COCH3]

✍ Scribed by Stephen P. Collingwood; Stephen G. Davies; Simon C. Preston

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 143 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)94501-5

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✦ Synopsis

The lithium enolate derived from the homochiral iron acetyl complex S-[(q5-C5H5)-Fe(CO)(PPh3)COCH3] reacts preferentially (40: 1) with the R-enantiomer of racemic t-butyl 2bromopropionate.

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