New 1D complexes are obtained from the reaction of 1,1ะbiphenyl-2,2ะ-dicarboxylic acid (diphenic acid) with KOH and [ under hydrothermal conditions. Compounds 1 and 2 are isostructural and their structure consists of stacked helical chains of octahedral metal(II) ions. Magnetic measurements show th
โฆ LIBER โฆ
Idle spin behavior of the shifted hexagonal tungsten bronze type compounds FeIIFeIII2F8(H2O)2 and MnFe2F8(H2O)2
โ Scribed by M. Leblanc; G. Ferey; Y. Calage; R. De Pape
- Publisher
- Elsevier Science
- Year
- 1984
- Tongue
- English
- Weight
- 565 KB
- Volume
- 53
- Category
- Article
- ISSN
- 0022-4596
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The iron-substituted sandwich-type polyoxometalate (POM), comprised of the main group element Sb(III) as the central heteroatom, [Sb 2 W 20 Fe 2 O 70 (H 2 O) 6 ] 8ร (Sb 2 W 20 Fe 2 ), is one of the Krebs-type derivatives. For the first time, the POMs redox electrochemistry has been elucidated under