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Identification of the composition of oligosaccharides and polysaccharides by pyrlysis/capillary gas chromatography

✍ Scribed by R.J. Helleur; D.R. Budgell; E.R. Hayes

Publisher: Elsevier Science
Year: 1987
Tongue: English
Weight: 390 KB
Volume: 192
Category: Article
ISSN: 0003-2670
DOI: 10.1016/s0003-2670(00)85726-8

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✦ Synopsis

Pyrolysis/capillary gas chromatography is used for the characterization of the monomer composition of various oligosaccharides and polysaccharides including glucosecontaining disaccharides, glucans, a galactomannan and an arabinogalactan. The chromatograms showed many common pyrolysis products, but also unique anhydrosugar products (e.g., 1,6-anhydroglucopyranose, 1,4-anhydroarabinopyranose, 2,6-anhydrofructofuranose) derived from each type of saccharide unit present in the samples. Reasonable values of the monomer composition of the polysaccharide can also be obtained from the pyrograms. The method is rapid and direct, requiring no sample preparation.

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