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Hypervalent iodine oxidation of trimethylsilyl enol ethers of ketones: A direct synthesis of α-keto triflates

✍ Scribed by Robert M. Moriarty; W. Ruwan Epa; Raju Penmasta; Alok K. Awasthi

Publisher: Elsevier Science
Year: 1989
Tongue: French
Weight: 201 KB
Volume: 30
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(01)80277-x

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✦ Synopsis

a-Trifluoromethanesulfonoxy ketones (a-keto triflates) have been synthesized

under very mild conditions by the reaction of silyl enol ethers of ketones and nimethylsilyl trifluormethanesulfonate/iodosobenzene in dichloromethane.

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