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Hypervalent iodine oxidation of aryl methyl ketones: A convenient route to methyl α-methoxyarylacetatos

✍ Scribed by Om V Singh

Publisher: Elsevier Science
Year: 1990
Tongue: French
Weight: 189 KB
Volume: 31
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)89024-3

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✦ Synopsis

Hypervalent iodine oxidation

of aryl methyl ketones using two equivalents of iodosobenzene diacetate leads to 1.2-aryl migration followed by solvohyperiodination to yield the corresponding methyl a-methoxyarylacetates.

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