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Hypervalent iodine oxidation of 2-aryl-1,2,3,4-tetrahydro-4-quinolones: An expedient route to naturally occurring 4-alkoxy-2-arylquinolines

✍ Scribed by Rajender S. Varma; Dalip Kumar

Book ID: 104260234
Publisher: Elsevier Science
Year: 1998
Tongue: French
Weight: 190 KB
Volume: 39
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(98)02059-0

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✦ Synopsis

Easily accessible 2-aryl-l,2,3,4-tetrahydro-4-quinolones are readily oxidized to the corresponding 4-alkoxy-2-arylquinolines using a relatively safe hypervalent iodine reagent, [hydroxy (tosyloxy)iodo]benzene (HTIB), in high yields, thus providing a concise route to an important class of naturally occurring alkaloids.

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