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ChemInform Abstract: Microwave-Assisted Isomerization of 2′-Aminochalcones on Clay: An Easy Route to 2-Aryl-1,2,3,4-tetrahydro-4-quinolones.

✍ Scribed by R. S. VARMA; R. K. SAINI

Publisher
John Wiley and Sons
Year
2010
Weight
28 KB
Volume
28
Category
Article
ISSN
0931-7597

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Reaction of 2,2,6-Trimethyl-4H-1,3-dioxin-4-one with Imines: An Easy Route to Enamides. -Thermolysis of the dioxin (I) generates an acylketene which is readily trapped by imines to give the N-alkenyl acetoacetamides (III). They are useful intermediates in oxidative radical cyclizations leading to .