Hydrothermal Vanadium Fluoride Chemistry: Four New V3+ Chain Structures.
β Scribed by David W. Aldous; Nicholas F. Stephens; Philip Lightfoot
- Book ID
- 102006877
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 20 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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β¦ Synopsis
Abstract
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Two new potassium vanadium phosphates have been prepared and their structures have been determined from analysis of single crystal X-ray data. The two compounds, \(\mathrm{K}_{3}(\mathrm{VO})\left(\mathrm{V}_{2} \mathrm{O}_{3}\right)\) \(\left(\mathrm{PO}_{4}\right)_{2}\left(\mathrm{HPO}_{4}\right)\
A new arsenic-vanadium clusters, [NH 2 (CH 2 CH 2 ) 2 NH 2 ] 3 [As 8 V 14 O 42 (SO 4 )]$6.5H 2 O (1), have been hydrothermally synthesized and characterized by IR, elemental analysis, TGA, magnetic property, and single crystal X-ray diffraction analysis. Crystal data: Monoclinic, P2(1)/n, aZ21.963(2