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Hydrothermal synthesis and structure determination of Ag3(VVO2){O3PCH2PO3} or MIL-42: a new vanadium(V) methylendiphosphonate inserting silver cations

✍ Scribed by Karin Barthelet; Didier Riou; Gérard Férey

Book ID: 114370300
Publisher: Elsevier Science
Year: 2001
Tongue: English
Weight: 582 KB
Volume: 3
Category: Article
ISSN: 1293-2558
DOI: 10.1016/s1293-2558(00)01132-8

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Fe 2 (H 2 O) 2 (O 3 P+CH 2 +PO 3 H) 2 ](H 2 O) 2 or MIL-13 was prepared hydrothermally (120 h at 473 K). Its structure was determined by powder X-ray di4raction. This compound crystallizes in the triclinic system (P-1) with the following cell parameters: a ‫؍‬ 9.8487(6) A > , b ‫؍‬ 8.0308(5) A > , c