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Hydrothermal Synthesis of Microporous Transition Metal Squarates: Preparation and Structure of [CO3(μ3-OH)2(C4O4)2]·3H2O

✍ Scribed by Siegfried O. H. Gutschke; Dr. Michel Molinier; Dr. Annie K. Powell; Dr. Paul T. Wood


Publisher
John Wiley and Sons
Year
1997
Tongue
English
Weight
267 KB
Volume
36
Category
Article
ISSN
0044-8249

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Single crystals of Lu(ClO 4 ) 3 ´3 H 2 O were obtained by slow dehydration of Lu(ClO 4 ) 3 ´6 H 2 O at 140 °C under flowing argon. The compound crystallizes in the triclinic crystal system (P1, Z = 2, a = 750.3(1), b = 838.4(1), c = 1054.6(2) pm, a = 79.77(2)°, b = 79.18(2), c = 63.83(2), R all = 0.