The U(IV) 6uorides (C 5 H 14 N 2 ) 2 U 2 F 12 ' 5H 2 O (AU1-2) and (NH 4 ) 7 U 6 F 31 have been prepared from the reaction of UO 3 with HF and homopiperazine (C 5 H 12 N 2 ) at 1803C in aqueous media. AU1-2 contains dodecahedral UF 8 units that share two edges to form 1 [UF 4 F 4/2 ] one-dimensional
Hydrothermal Synthesis of (C 6 N 2 H 14 ) 2 (U VI2 U IV O 4 F 12 ), a Mixed-Valent One-Dimensional Uranium Oxyfluoride
β Scribed by Allen, Simon; Barlow, Stephen; Halasyamani, P. Shiv; Mosselmans, J. Frederick W.; O'Hare, Dermot; Walker, Susan M.; Walton, Richard I.
- Book ID
- 126023720
- Publisher
- American Chemical Society
- Year
- 2000
- Tongue
- English
- Weight
- 136 KB
- Volume
- 39
- Category
- Article
- ISSN
- 0020-1669
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
The hydrothermal syntheses and structures of two new open-framework iron phosphates, I, [C 6 N 2 H 14 ][Fe III 2 F 2 (HPO 4 ) 2 (H 2 PO 4 ) 2 ].2H 2 O, II, and [C 6 N 2 H 14 ] 2 [Fe III 3 (OH)F 3 (PO 4 ) (HPO 4 ) 2 ] 2 . H 2 O, are presented. The structures of both I and II consist of FeO 4 F 2 octa