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Low-Dimensional Organically Templated Uranium Fluorides (C 5 H 14 N 2 ) 2 U 2 F 12 ·2H 2 O and (C 2 H 10 N 2 )U 2 F 10 : Hydrothermal Syntheses, Structures, and Magnetic Properties

✍ Scribed by Almond, Philip M.; Deakin, Laura; Porter, Melissa J.; Mar, Arthur; Albrecht-Schmitt, Thomas E.

Book ID
126219488
Publisher
American Chemical Society
Year
2000
Tongue
English
Weight
129 KB
Volume
12
Category
Article
ISSN
0897-4756

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Hydrothermal Syntheses, Structures, and
Hydrothermal Syntheses, Structures, and Magnetic Properties of the U(IV) Fluorides (C5H14N2)2U2F12·5H2O and (NH4)7U6F31
✍ Philip M. Almond; Laura Deakin; Arthur Mar; Thomas E. Albrecht-Schmitt 📂 Article 📅 2001 🏛 Elsevier Science 🌐 English ⚖ 414 KB

The U(IV) 6uorides (C 5 H 14 N 2 ) 2 U 2 F 12 ' 5H 2 O (AU1-2) and (NH 4 ) 7 U 6 F 31 have been prepared from the reaction of UO 3 with HF and homopiperazine (C 5 H 12 N 2 ) at 1803C in aqueous media. AU1-2 contains dodecahedral UF 8 units that share two edges to form 1 [UF 4 F 4/2 ] one-dimensional