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Hydrosilylation of ketones catalyzed by tricarbonyl(naphthalene)manganese cation

✍ Scribed by Seung Uk Son; Se-Jung Paik; Young Keun Chung


Publisher
Elsevier Science
Year
2000
Tongue
English
Weight
66 KB
Volume
151
Category
Article
ISSN
1381-1169

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Convenient Enantioselective Hydrosilylat
✍ Jadwiga Gajewy; Marcin Kwit; Jacek GawroΕ„ski πŸ“‚ Article πŸ“… 2009 πŸ› John Wiley and Sons 🌐 English βš– 303 KB πŸ‘ 2 views

## Abstract magnified image Chiral macrocyclic tetra‐ and hexamine macrocycles derived from __trans__‐1,2‐diaminocyclohexane (DACH) in complexes with diethylzinc efficiently catalyze the asymmetric hydrosilylation of aryl alkyl ketones with enantiomeric excess of the product up to 89%. The cyclic