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Hydrosilylation of Ketones Catalyzed by C2-Symmetric Proline-Derived Complexes.

✍ Scribed by Li Gan; Michael A. Brook


Publisher
John Wiley and Sons
Year
2007
Weight
23 KB
Volume
38
Category
Article
ISSN
0931-7597

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Convenient Enantioselective Hydrosilylat
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## Abstract magnified image Chiral macrocyclic tetra‐ and hexamine macrocycles derived from __trans__‐1,2‐diaminocyclohexane (DACH) in complexes with diethylzinc efficiently catalyze the asymmetric hydrosilylation of aryl alkyl ketones with enantiomeric excess of the product up to 89%. The cyclic