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Hydrosilylation of 1-hexyne catalyzed by rhodium and cobalt-rhodium mixed-metal complexes. Mechanism of apparent trans addition

✍ Scribed by Ojima, Iwao; Clos, Nuria; Donovan, Robert J.; Ingallina, Patrizia


Book ID
121009830
Publisher
American Chemical Society
Year
1990
Tongue
English
Weight
869 KB
Volume
9
Category
Article
ISSN
0276-7333

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## Abstract The Ξ·^4^‐diphosphacyclobutadiene complexes [M(Ξ·^5^‐C~5~R~5~)(Ξ·^4^‐P~2~C~2~Bu)] (M ο£Ύ Co, Rh; R ο£Ύ H, Me), react with Rh(I), Pt(O), and Pt(II) centers via the phosphorus lone paris of the rings of afford mixed metal complexes. The crystal and molecular structure of the novel hexarhodium co