Mechanism of the Hydroxycarbonylation of 1-Hexene Catalyzed by Immobilized Rhodium Complexes of Pyridine Ligands
β Scribed by Alvaro J. Pardey; Fernando Hung-Low; Gabriela C. Uzcategui; Marisol C. Ortega; Clementina Longo
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 18 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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## Abstract Application of new chiral ligands (__R__)β(β)β**12βa** and (__S__)β(+)β**12βc** (VALDY), derived from amino acids, to the title reaction, involving cinnamyl (linear) and isocinnamyl (branched) type substrates (**4** and **5** β **6**), led to excellent regioβ and enantioselectivities (>