Hydrolysis of α- and β-Glycosides. New Experimental Data and Modeling of Reaction Pathways.
✍ Scribed by Pierre Deslongchamps; Shigui Li; Yves L. Dory
- Publisher
- John Wiley and Sons
- Year
- 2004
- Weight
- 53 KB
- Volume
- 35
- Category
- Article
- ISSN
- 0931-7597
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract The hydrolysis reactions of __N__‐(__O__,__O′__‐diisopropyl)phosphoryl‐__L__‐__α__‐alanine (DIPP‐__L__‐__α__‐Ala), __N__‐(__O__,__O′__‐diisopropyl)‐ phosphoryl‐__D__‐__α__‐alanine (DIPP‐__D__‐__α__‐Ala), __N__‐(__O__,__O′__‐diisopropyl)phosphoryl‐__β__‐alanine (DIPP‐__β__‐Ala) and __N__
## Abstract In this study, (__E__)‐ and (__Z__)‐enones carrying only a phenyl substituent at their C(__β__) atom were treaced with dimethyl diazomalonate in the presence of (acetylacetonato)copper(II). According to the configuration of the starting enones, the products were dioxole or dihydrofuran
A quantitati¨e ¨alidation procedure for comparisons of modeled and experimental data is described. This produces se¨eral le¨els of information, from a straightforward numerical assessment to detailed diagnostic data. Results show that this method has significant ad¨antages o¨er a ¨isual approach in